Environmental Quality Branch
VEHICLE EMISSIONS
No
Room To Breathe: Photochemical Smog and Ground-Level
Ozone
Last
Updated: June 2008
Introduction
You
can see it as you drive into the Lower Fraser Valley
on a warm summer day: a brownish haze that hangs
over the city, marring the beauty of blue sky and mountains.
It's
called photochemical smog and it's not just unsightly, it's unhealthy. Nor is Greater Vancouver the
only area that suffers from smog. In fact, this serious
form of air pollution occurs in many major urban and
industrial areas in Canada.
Each
one of us can help bring the fresh air back to our land.
That's because we each contribute to creating it in
the first place. The exhaust from our automobiles
is the number one cause.
This
brochure describes what smog is, how it affects our
health and the environment, and most important, how YOU can become part of the solution.
Photochemical Smog
Photochemical
smog occurs in the lower portion of our atmosphere,
known as the troposphere. Its main unhealthy ingredient
is "ground-level ozone."
Ozone
is formed by the reaction of volatile organic compounds
(VOCs) and nitrogen oxides (NOx) in the presence of
sunlight and warm temperatures. A stagnant air mass — the result of high atmospheric pressure and
light winds — keeps the pollution from being dispersed.
The ideal conditions for ozone buildup occur from late
spring to early fall in most Canadian cities.
It
should be noted that VOCs, NOx and ozone occur naturally
in the lower atmosphere, too. However, human activities — fossil fuel use, in particular — have
greatly increased the amounts.
VOCs
(also called hydrocarbons) are the most important constituents
of oil and natural gas. The major human-caused source of
VOC emissions is motor vehicles. Evaporation of gasoline,
solvents, oil-based paints and hydrocarbons from the
petrochemical industry are also significant sources.
Like
VOCs, NOx are mainly produced by oil and gas, but in
this case it's burning the fuel that does it. The exhaust
from fossil fuel combustion in our motor vehicles is
the primary source, followed by fuel burning in homes,
businesses, factories and power plants.
Ironically,
although we humans are causing too much ozone in the
troposphere, we're triggering ozone destruction in the
upper reaches of our atmosphere: the stratosphere.
Ozone depletion in the stratosphere is allowing more
and more of the sun's potentially damaging ultraviolet
radiation to reach the earth's surface. Its cause is
the discharge of ozone-destroying chemicals such as
chlorofluorocarbons (CFCs) and halons.
There
is, unfortunately, no way to siphon the over-abundance
of ground-level ozone in the troposphere up to the stratosphere,
to fill in the depleted ozone layer. What we have to
do is get at the root of the problem — human beings
and their activities. If we want to "breathe easy," we have to clean up our own act.

More Than an Urban Problem
Ground-level
ozone collects over the cities that produce large amounts
of VOCs and NOx. But it can also migrate up to several
hundred kilometres downwind. Topography (such as valleys)
and meteorological conditions (such as clear skies and
stagnant air) promote ozone buildup. Sometimes the smog
is most intense far from its source.
The
Lower Fraser Valley has one of the worst smog problems
in Canada, surpassed only by the urban belt extending
from Windsor to Quebec City. Strange as it may seem,
though, downtown Vancouver does not experience the highest
ozone levels in the area. The middle and eastern portions
of the Lower Fraser Valley bear the brunt.
The
reason is that it takes time for the sun-driven chemical
reaction to transform the NOx and VOCs emitted from
Greater Vancouver into ground-level ozone. While sea
breezes blow eastward, this process of transformation
takes place and ozone is gradually produced. The mountains
then trap the pollution in the eastern part of the valley.
Hence, the greatest concentration of ozone often occurs
in the vicinity of Coquitlam and Port Moody.
What
about other cities in British Columbia? Topography and
summer weather conditions will predispose many of our
urban areas to smog, if the population and automobile
emissions become large enough.
Early
indications from the Okanagan and Greater Victoria (the
places most likely to experience smog, at present) suggest
that ozone is not yet a significant issue. However,
the growth rates in both locales and the general increase
in motor vehicle use make it important to take preventive
action now, before smog can become a problem. The same
is true for cities across British Columbia. Regional
transportation planning is especially crucial.

How Does Smog Affect Us?
Human
Health
Low
concentrations of ground-level ozone can irritate the
eyes, nose and throat. As smog increases, it can trigger
more serious health problems, including:
- asthma,
bronchitis, coughing and chest pain;
- increased
susceptibility to respiratory infections; and
- decreased
lung function and physical performance.
Prolonged
exposure can eventually damage lung tissue, cause premature
aging of the lungs and contribute to chronic lung disease.
Children, the elderly and people with impaired lung
function are considered to be most at risk.
Vegetation and Materials
Sensitive
crops, trees and other vegetation are harmed at lower
ozone concentrations than human health is. Ground-level
ozone can damage leaves, and reduce growth, productivity
and reproduction. It can cause vulnerability to insects
and disease, and even death.
When
ozone levels are fairly high over a long period, agricultural
crops can suffer significant harm. In the Lower Fraser
Valley, for example, the agricultural production that
could be lost each year to smog damage is estimated
to be worth several million dollars.
Smog
can also accelerate the deterioration of rubber, fibres,
plastics, paints and dyes.
The Enhanced Greenhouse Effect and Acid Rain
The
pollutants we spew into our atmosphere are implicated
in more than one environmental problem. Ozone, for example,
is not only a major component of smog; it also contributes
to global climate change. Similarly, NOx —
one of the building blocks of ground-level ozone —
plays a major role in creating acid rain.

Putting the Lid on Smog
It's
tempting to retreat into apathy to escape the army of
environmental ills confronting us. But that will just
make the problem worse — for us, our children, and the
children of tomorrow. Local smog problems alone won't
destroy life as we know it. However, in combination
with other pollutants they may inflict a serious wound.
This
is a time of supreme challenge for humanity. Never before
have we had the power to destroy the planet's delicately
balanced ecosystem. We also have the power to save it.
But we need to act now. All of us.
Caring
for the environment begins at home and with each individual.
Opting for a more environmentally friendly lifestyle
will take a little effort but think of the reward: fresh,
clean air for present and future British Columbians!
Reducing
vehicle emissions is the key to improving air quality,
since motor vehicles are the largest single source of VOCs
and NOx. (They also emit a variety of other contaminants,
including harmful particulates and carbon monoxide.)
In
the Lower Fraser Valley, 75% of local air pollution
(containing the chemicals which lead to ozone formation)
is caused by motor vehicles. Rush-hour commuters in
private cars are the major culprits in producing vehicle
emissions. Most of those cars hold only one person.
What a waste!
Even
if each of us leaves our car at home just once a week — opting instead for the bus, bicycle or carpool — the
reduction in emissions will be substantial. Our pocketbook
will benefit, too!
Cutting
down on our smog-producing activities is especially
important on days when the potential for smog formation
is high — such as during hot sunny and calm weather.
To
find out more on how YOU can help clear the air, read
on. Remember, conserving energy is crucial!

Getting Around
- Break the automobile addiction! Use public transit or join a carpool. Better yet, ride your bike or use your feet. Even if each of us leaves our car at home
just once a week, the reduction in emissions will be substantial.
- When
you have to drive, save energy by combining errands. Parking and
walking is easier on the air than sitting with your
motor running (idling) at drive-through restaurants
and banks.
- When starting your car on a cold day, warm it up for only 30 seconds, and then drive it. Warming it up for any longer than that (idling) is not effective
or good for your modern car. (If the outside temperature is extremely cold, longer idling is appropriate.)
- And speaking of idling — running your engine needlessly when you're waiting for someone, for example — avoid it whenever
you can. Idling for more than 10 seconds contributes to local air pollution and climate change. It also wastes fuel and money. For more information, visit Idle
Free BC.
- Slow down when you drive. You'll use less gas and thereby produce less pollution.
- Prevent gas leaks and evaporation by resisting the temptation to overfill your gas tank. Gas emits VOCs, one of the major building blocks of smog.
- Keep your vehicle engine in top condition with a regular tune-up and an annual emissions check.
- Use radial tires to cut down on tire drag and save gas. Inflate your tires to the manufacturer's recommended pressure. You'll save up to 10% on fuel
consumption.
- Looking for a new vehicle? Go for a smaller, fuel-efficient model with low emissions. Buy for your regular use, rather than getting a larger vehicle you
rarely need (and which you can borrow or rent).
- Switch to cleaner fuels — low-polluting fuels that can be used in motor vehicles instead of gasoline or diesel. Examples include ethanol, methanol,
natural gas and electricity.
- Rather than owning a vehicle, consider joining a car-sharing co-operative. You'll end up driving less, which is good news for the air. You'll also save money.
- Support
urban planning that lowers automobile use, such as more cycling lanes, better public transit
systems and vehicle-free areas.

Home Sweet Home
- Conserve energy! Some sources indicate that Canadians use more energy, per capita, than any other people in the world. Most of our energy comes from the burning of fossil
fuels (oil, coal and gas).
- The home is the third biggest energy hog in the country, after industry and transportation. Most of our household energy is used for space heating, but a lot is wasted because
of inefficient house construction and poor heating methods. The average Canadian home loses about a quarter of its heat through air leaks.
- It doesn't have to be this way. An energy-efficient house that traps passive solar energy and retains it by minimizing air leaks can reduce annual energy consumption
by over half that of a conventional home. This can create substantial benefits for both the atmosphere and our energy bills.
- To keep your home warm in winter and cool in summer, follow these tips:
- Insulate your home effectively and install a vapour barrier.
- Caulk or weather strip cracks and holes, as well as windows and doors.
- Install windows that are efficient at preventing heat loss. Plastic insulating sheets that can be attached to window frames are also effective heat savers.
- Close heating vents and doors to rooms you aren't using.
- Plant a deciduous tree beside your home to keep out the sun in summer and let in the warmth during winter.
- Convert to cleaner, more efficient fuels. Natural gas is an interim solution. Though it's more efficient than oil and creates fewer emissions, gas is still a fossil fuel
and releases large quantities of CO2 and other pollutants.
- Hydroelectricity is preferable to both natural gas and oil for heating, although it has environmental repercussions, too. Solar energy is another viable option.
- Set your thermostat no higher than 20°C during the day, and turn it down when you're out or asleep.
- Have your furnace serviced regularly to ensure efficient operation.
- Keep your water heater at 50°C, and use cold water whenever possible.
- Avoid using gas-powered garden tools. The engine in a gas-powered lawn mower produces eight times the pollution that a car engine does. Use a push lawnmower
instead, a rake instead of a leaf blower, and clippers instead of a weed eater. You’ll get more exercise, and you'll be able to hear the birds!
- Paint
with water-based (latex) paint rather than the oil-based
variety. The latter contains three to five times more
toxic solvents than water-based paint. Close
paint cans tightly. An open 4.5 litre can of paint
emits up to a kilogram of VOCs by the time all the
paint has dried up.
- Steer clear of aerosol cans containing products such as paint, deodorant and hair spray. The gases that make the product shoot out contribute to smog.
- Buy
products with less packaging. It takes a lot of energy
to make packaging, and VOCs are generated during the
printing process.
- Let
your personal commitment to a healthy environment
reach out into your society. Act as an example: change your behaviours to be more "green." Tell your friends and
family why it's so important to reduce emissions — and explain how they can help.

For
More Information:
Environmental Quality Branch
Ministry of Environment
Government of British Columbia
PO Box 9341
Stn Prov Govt
Victoria, British Columbia
Canada V8W 9M1
http://www.env.gov.bc.ca/air
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