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Table 4.1 Fate of Chlorophenols in Water

line

Process

MCPs

DCPs

TCPs

TTCPs

PCP

1/2 life in water

<1 to 26 days

>6 days

>9 to 35 days

>3.5 months

<3.5 months
if aerobic

1/2 life in
sediment

     

years if
organic

years if
organic

1/2 life in fish tissue

2 days

2 days

10 days

10 days

10 days

biological
concentration
factor

214 in
bluegill
sunfish

occurs in
marine biota
and crops

2,4,5-TCP
170-1900 in
fish.
2,4,6-TCP
51-442
in plants.
115 to 12180 in fish and 3000
in inverts.

20-221 in fish
muscles
40-8590 in
fish liver.
1000
in leeches
1250
in Cladophora

10-15000 in
fish, liver
high and muscle low,
lower still in
algae and
inverts.

Table 4.1 (continued)

Process

MCPs

DCPs

TCPs

TTCPs

PCP

loss by
evaporation
or by volatilization

not important

not important

not important

not important

of little
importance in shallow
water at
pH 5, not important over pH 7.

hydrolysis and oxidation

not important

not important

not important

not important

not important

photolysis

unknown in nature, occurs in the laboratory

unlikely
to be
significant in nature

occurs in
nature but
significance is not known

unlikely to be of significance in nature

important in clear, shallow, neutral to
alkaline
waters.

sorption

there is a
tendency
to attach
to organic
particles

may be
important
in organic
sediments

observed
in lake and river
sediments

observed in
river and lake sediments

important,
observed in acidic and in
contamin-ated sites

biological
degradation

occurs in the laboratory the rate in nature is
not known.

rate depends
on water
quality and on prior
bacterial
exposure

reported in
water, soil
and bacterial
cultures,
likelier in
stagnant
waters.

reported in soil and bacterial
cultures, slower in aquatic systems.

occurs in
culture and in nature, best at higher
temperatures
and when
aerobic.

From Reference 220.

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