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Water Quality

Ambient Water Quality Guidelines for Chlorophenols

First Update

TABLE OF CONTENTS


Recommended Water Quality Guidelines
Guidelines for Water
Interim Aquatic Life Toxicity Guidelines ** for Chlorophenols
Recreation
Industrial
Abbreviations and Acronyms
Definitions

1. Introduction
2. Characteristics
3. Dissemination of the Chlorophenols
4. The Fate of Chlorophenols in the Environment
5. Biological Effects of Chlorophenols
6. Drinking Water
7. Terrestrial Life
8. Aquatic Life
9. Irrigation
10. Recreation
11. Industrial
12. Research Needs

References
Alphabetical Index of Authors of Reference

TABLES

Table 1.1.1 Summary: Water Quality Guidelines for Chlorophenols.
Table 1.1.2 Interim Aquatic Life Toxicity Guidelines ** for Chlorophenols.
Table 1.1.3 Taste Guidelines for Chlorophenols in Fish Muscle.
Table 1.3 Relative Toxicity of the Chlorophenols in Several Biological Test Systems.

Table 2.1.1 The Chlorophenols: Formulae, Names and Molecular Weights.
Table 2.1.2 List of Alternate names for the Chlorophenols, as found in the literature (655, and other references).
Table 2.3 Characteristics of the Chlorophenols.
Table 2.4 QSAR Analyses of the Relative Toxicity of the Chlorophenols.

Table 3.2 Some Commercially Registered Products Containing Chlorophenols.
Table 3.3.1 Analyses of 2,4-DCP and 2,4-D Acid Samples for Chlorinated
Table 3.3.2 The Concentrations of Chlorophenols found in Commercial Products
Table 3.3.3 Contaminants Present in Commercial PCP Products.
Table 3.3.4 Dioxins Present as Impurities in Commercial PCP Products.
Table 3.3.5 Analyses of polychlorinated phenols for Dioxins and Furans-1977.
Table 3.5.1 Chlorophenol Levels Detected in Fraser River Water.
Table 3.5.2 PCP, TTCP and TCP levels in Water and Sediment at SW BC Sites in 1978.
Table 3.5.3 PCP and TTCP Contamination of Canadian Foods.
Table 3.5.4 Chlorophenols Detected in Fraser River Biota.
Table 3.6.1 Summary of Chlorophenol Data from the Fraser Estuary, 1973-1987.

Table 4.1 Fate of Chlorophenols in Water.
Table 4.1.5.1 Adsorption of Chlorophenols on Bentonite Organic Clays.
Table 4.1.5.2 Partitioning of TCPs and TTCPs in the Lower Rhine River.
Table 4.2.1 Chlorophenol Degradation Studies in Soil and Sludge.
Table 4.2.3.1 Calculated Chlorophenol Bioconcentration Factors.
Table 4.2.3.2. PCP Tissue levels and Bioaccumulation Factors Relative to the Sediments.
Table 4.2.3.3. TTCP Tissue levels and Bioaccumulation Factors Relative to the Sediments.
Table 4.2.3.4 Bioaccumulation Factors for PCP Relative to Water.
Table 4.2.3.5 Bioaccumulation Factors Relative to Water for Chlorophenols except PCP.
Table 4.2.3.6 Bioaccumulation Factors for Chlorophenols Relative to the Sediments.
Table 4.2.3.7 The Effect of pH on Chlorophenol Toxicity in guppies, Lebistes reticulata.
Table 4.2.3.8 Ratios of Chlorophenols in Water and Rainbow Trout Tissues.
Table 4.2.3.9 PCP Uptake Rates in Rainbow Trout, Oncorhynchus mykiss, Tissues.
Table 4.2.3.10 PCP Elimination Rates in Rainbow Trout, Oncorhynchus mykiss, Tissues.
Table 4.2.3.11 PCP Uptake Rates in Bluegill Sunfish, Lepomis macrochirus, Tissues.
Table 4.2.3.12 PCP Elimination Rates in Bluegill Sunfish, Lepomis macrochirus, Tissues.
Table 4.2.3.13 PCP Accumulation in a Fish, Shrimp and Oyster from flowing seawater, over 96 hours.
Table 4.2.4.1 Depuration 1/2 Lives (DP50) of Chlorophenols in Animals.

Table 5.0 Cytotoxicity, Fetotoxicity/Embryotoxicity and Teratogenicity of the Chlorophenols.
Table 5.6 Ames Mutagenicity Assays using Salmonella typhimurium.
Table 5.8.1 The Product of the LC100 and the time it takes to kill fish with PCP.

Table 6.2.1 Taste Thresholds for Chlorophenols in Drinking Water.
Table 6.2.2 Odour Thresholds for Chlorophenols in Drinking Water.
Table 6.3 Literature Guidelines for Chlorophenols in Drinking Water.

Table 7.1 The Toxicity of some Commercial Chlorophenol Preparations to Pulp and Paper Fungi and Bacteria.
Table 7.1.1 The Effect of Chlorophenols on Fungal Growth.
Table 7.1.2 The Effects of Chlorophenols on Bacteria.
Table 7.2 The Effect of Chlorophenols in Water on the Germination of Radish and Sorghum Seeds.
Table 7.5.1 The Effects of Pentachlorophenol on Mammals.
Table 7.5.2 The Effects of Chlorophenols on Mammals and Birds.
Table 7.7 Chlorophenol limits for Humans as Recommended in the Literature.

Table 8.1.2 The Effects of Chlorophenols on Marine Algae.
Table 8.1.3.1 The Effects of Chlorophenols on Marine Molluscs.
Table 8.1.3.2 The Effects of Chlorophenols on Marine Worms.
Table 8.1.3.3 The Effects of Chlorophenols on Marine Crustaceans.
Table 8.1.3.4 The Effects of PCP on the Marine Polychaete Worm, Ophryotrocha diadema.
Table 8.1.3.5 The Effects of Chlorophenols on Miscellaneous Marine Invertebrates.
Table 8.1.3.6 Acute Toxicity of Chlorophenols to the Grass Shrimp Palaemonetes pugio.
Table 8.1.4 The Effects of Chlorophenols on Marine Fish.
Table 8.2.2 The Effects of Chlorophenols on Freshwater Algae.
Table 8.2.5.1 The Effects of Chlorophenols on Aquatic Plants.
Table 8.2.5.2 PCP Concentration vs. Effects on Lemna minor, duckweed.
Table 8.2.6.1 The Effects of Chlorophenols on Aquatic Insects.
Table 8.2.6.2 The Effects of Chlorophenols on Freshwater Molluscs.
Table 8.2.6.3 The Effects of Chlorophenols on Protozoans and Coelenterates.
Table 8.2.6.4 The Effects of Chlorophenols on Aquatic Worms.
Table 8.2.6.5 The Effects of Chlorophenols on Aquatic Crustaceans.
Table 8.2.6.6 The Effects of Chlorophenols on Cladocerans (except Daphnia magna).
Table 8.2.6.7 The Effects of Chlorophenols on Daphnia magna.
Table 8.2.6.8 The Effects of Pentachlorophenol on the Snail Lymnaea acuminata.
Table 8.2.6.9 The Effects of pH and Temperature on the mg/L of PCP needed to demonstrate a 96-h LC50 response in the Snail Physa gyrina.
Table 8.2.6.10 Summary of the Cladoceran Data.
Table 8.2.6.11. The Effect of temperature, duplicate testing and test duration on the LC50 in mg/L to Sodium Chlorophenate using Daphnia magna.
Table 8.2.6.12. The Effect of temperature, duplicate testing and test duration on the LC50 in mg/L to Sodium Chlorophenate using Daphnia pulex.
Table 8.2.7 The Effects of Chlorophenols on Amphibians.
Table 8.2.8.1 The Effects of Chlorophenols on Fish...CARP.
Table 8.2.8.2 The Effects of Chlorophenols on Fish...MISCELLANEOUS SPECIES.
Table 8.2.8.3 The Effects of Chlorophenols on Fish...Lepomis macrochirus (bluegill sunfish).
Table 8.2.8.4 The Effects of Pentachlorophenol on Fish...Rasbora daniconius neilgeriensis.
Table 8.2.8.5 The Effects of Chlorophenols on Fish...Pimephales promelas (fathead minnows).
Table 8.2.8.6 The Effects of Chlorophenols on Fish...Notopterus notopterus.
Table 8.2.8.7 The Effects of Chlorophenols on Fish...Oncorhynchus Sp. (trout and salmon).
Table 8.2.8.8 The Effects of Chlorophenols on Fish...Poecilia (Lebistes ) reticulata (guppies).
Table 8.2.8.9 The Effects of Chlorophenols on Fish...Ictalurus punctatus (channel catfish).
Table 8.2.8.10 The Effects of Chlorophenols on Fish...Salmo Sp.
Table 8.2.8.11 The Effects of Pentachlorophenol on Fish...Notropis Sp.
Table 8.2.8.12 Summary of the Fish Data from Tables 8.2.8.1 to 8.2.8.11.
Table 8.3.1 Taste Thresholds for Chlorophenols in Fish Muscle.
Table 8.3.2 Literature Water Levels and Guidelines to Prevent Taste Problems in Fish Flesh.
Table 8.4.1 Literature Guidelines or Objectives for the Protection of Aquatic Life from Chlorophenols.
Table 8.5.1 Raw Aquatic Life Toxicity Guidelines for Chlorophenols in µg/L at 10C.
Table 8.5.1.1 Constants used in Calculating Raw Aquatic Life Toxicity Guidelines for Chlorophenols at different pH values.
Table 8.5.2 Recommended Chlorophenol Guidelines to Prevent Tainting of Fish Muscle.
Table 8.6.1 Calculated or Experimental No Observed Effect and Non-Lethal Levels of Chlorophenols to Freshwater Life.
Table 8.6.2 The Lowest Literature LC50 values for Freshwater Life.
Table 8.6.3 The Lowest Literature Effect Level for Freshwater Life.
Table 8.6.4 The Lowest Literature LC50 values for Marine Life.
Table 8.6.5 The Lowest Literature Effect Level for Marine Life.
Table 8.6.6 Chlorophenol Guidelines Calculations in µg/L.
Table 8.6.7 The Lowest Values found in the Literature for the Specified Response: in µg/L.
Table 8.6.8 Chlorophenol Guidelines: calculated in µg/L, at 10ºC, from pH 5.7 to pH 9.2.


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